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Draft report Mercury Sources and Regulations, 1999 Update


APPENDICES

Appendix A:  Mercury Use Tree

Appendix B: Industrial Sources of Mercury and Applicable Mercury-Specific Regulations

Appendix C:  Regulations on Products that Contain Mercury

Appendix D:  Examples of State Mercury Controls

Appendix E:  Federal Mercury Controls

Appendix F:  Voluntary Initiatives

Appendix G:  Bibliography

Appendix H:  Mercury Waste RCRA Categories

 

DOWLOAD APPENDICES
NOTE:  these are Adobe PDF files

Appendix A  (Page 1)  (Page 2)  (Page 3)

Appendices B - F

Appendix G

Appendix H


 

 

 

Appendix A:

 

 

Appendix B:
Industrial Sources of Mercury and Applicable Mercury-Specific Regulations

Source

# Fac.
In Gl*

Origin/uses
Of Mercury

Air Releases **

Water
Discharges 
***

Waste
Management
****

Comments

MERCURY PRODUCTION

Primary Hg Production

 

Hg no longer produced from Hg ore; primary Hg recovered as by-product from gold ores.

NESHAPS: Hg air emissions shall not exceed 2300 grams Hg/24hrs for mercury ore processing facilities (40CFR61.52)

Hg effluent limits for primary precious metals and Hg subcategory (40CFR 421.250) and mercury ore subcategory (40CFR440.40)

Solid wastes from extraction, benificiation, and processing of ores exempt from RCRA hazardous waste regulations under Bevill amendment.

Mining facilities do not report chemical releases under TRI.

Secondary Hg Production

PA--2 IL--1 NY--1

Recycling/recovery of Hg containing products (e.g. dental amalgams, batteries); industrial waste and scrap (e.g. instrument and electrical manufacturing, waste, sludges from research labs).

 

Designated major source category of HAP emissions (CAA'112(c)).

Hg effluent limits for secondary Hg subcategory (40CFR421.200)--NSPS, PSNS based on amount of Hg produced or processed.

   

In-house Hg reclamation also occurs at industrial plants.

MN: drafting management standards for facilities recycling hazardous wastes. Hg refining plants in NY, PA, IL. MN also has three lamp recycling facilities.

Key:

Hg - Mercury,
CAA - Clean Air Act,
NESHAPS - National Emissions Standards for Hazardous Air Pollutants,
BIF - boilers and industrial furnaces,
TRI - Toxic Release Inventory,
MSW - municipal solid waste,
HAP - hazardous air pollutant,
MACT - maximum achievable control technology

Note: This table shows the significant sources of Hg releases by source category, and how those releases are currently regulated. Appendix A includes five categories of mercury sources: (1) Mercury Production, (2) Use as a Manufacturing Input, (3) Waste Disposal, (4) Release as a By-Product of Manufacturing, (5) Release as a By-Product of Electrical Generation. An asterisk (*) indicates that additional information appears on the last page.

Hg compound production

NY--3
OH--1
PA--1

Hg compounds include mercuric oxide, mercuric chloride, mercuric & mercurous sulfate, mercurous nitrate, organic Hg salt, thimersol

   

 

   

 

   

Many mercury compounds are imported.

Source

# Fac.
In Gl*

Origin/uses
Of Mercury

Air Releases **

Water
Discharges ***

Waste
Management****

Comments

MERCURY USE IN MANUFACTURING*****

Chemical And Allied Products

Chlorine/Caustic Soda Manufacture

(mercury cell chlor-alkali process)

WI--1 OH--1

Used as a catalyst in mercury cell process at chlor-alkali plants, which manufacture chlorine and sodium hydroxide. Hg cell process accounted for 14% of 1992 US chlorine production.

Hg emissions cannot exceed 2300g /24hrs; prescribed stack sampling methods required, and approved practices to meet specified ventilation emissions. (CAA (40CFR61, NESHAPS))

Existing Sources: BAT, BPT Hg effluent limits New Sources: NSPS, PSNS

No pretreatment standards for existing sources using mercury cell process (40CFR415.60)

Industry Specific: K071 and K106 are chlor-alkali wastes listed specifically for Hg. Land disposal restrictions for chlor-alkali process wastes effective May 1993

Largest single use of Hg in US

Impact of land disposal restrictions: some facilities are building mercury recovery plants; others are shipping wastes to Canada

Many Hg cell plants have changed to diaphragm cell process

Laboratory Uses

 

Used in instruments as reagent, catalyst, indicator, and for calibration, sealing, and radioactive diagnosis

   

No restriction --POTWs may develop public education campaigns for labs

   

Use declined from 32 metric tons in 1990 to 10 metric tons in 1991.

Paint

 

Mercury compounds used to control microbial growth in latex paint cans; prevent mildew growth on painted surfaces; anti-fouling agent in maritime paint

 

 

 

P092 - Phenylmercuric acetate (Hg compound used in paints) is an acute RCRA waste

$ All registrations for mercury biocides used in paint banned or voluntarily canceled by registrant

$ Hg in paints expected to continue declining as existing supplies depleted. Paint on buildings is demolition waste (not RCRA)

Other Chemical and
Allied Products

 

(see Table 5 and Appendix B for mercury- containing products.)

Chemical And Allied Products

Pesticides

 

Mercury compounds used as pesticides, biocides, fungicides

 

Process wastewater from manufacture of metallo-organic pesticides w/active ingredient containing Hg prohibited, subject to variances approved by EPA (40CFR455.30)

 

Voluntary cancellation of last two mercury-containing fungicides announced in November 1993

Electrical And Electronic Uses

Electric Lamps

 

Use: electrical conductor Hg emitted when lamps break

Products: High intensity lamps: mercury vapor lamps (used in motion picture production, photography, heat therapy); metal halide lamps; high pressure sodium lamps; incandescent lamp filaments, fluorescent lights

 

Waste streams from fluorescent bulb manufacturing exempted from pretreatment regulations (for all chemicals)

Hg levels in some products meet RCRA or state hazardous waste definition and require special management and disposal

Second largest source of mercury in MSW

Fluorescent bulbs are promoted for energy conservation, but considered hazardous waste due to Hg levels; In 1999, EPA included mercury-containing lamps the in universal waste rule.

MN has three lamp recycling facilities.

Wiring Devices & Switches

 

Hg encased in metal is used as conductor to close electrical circuit

Products: thermostats, Hg cells in smoke detectors, mercury arc rectifiers, silent switches, tilt switches, relays, cathode tubes used for radios, radar, & telecommunications equipment, electric toys

 

No pretreatment limits for switchgear wastestreams (for any chemicals)

 

Components found in a wide variety of equipment with electrical parts (e.g. white goods)

These are considered hazardous wastes under RCRA.

Battery Manufacturing

 

(1) Used as anode or electrolyte to prevent corrosion and hydrogen release; extends shelf-life; improves performance in extreme temperatures. Products: alkaline batteries. (2) used as cathode in Hg oxide batteries.

Products: mercuric oxide (Hg zinc) button batteries, silver oxide, zinc-air, carbon zinc batteries, mercuric oxide cannister batteries. Hg leaches from corrosion in landfill; volatilizes during combustion

 

Hg effluent limitations for LeClanche subcategory (zinc anode batteries w/acid electrolyte) (40CFR461.40); NSPS, PSNS, PSES based on mg/kg cell produced for specified operations only; no discharge allowed from nonspecified operations

Hg effluent limits for zinc subcategory (40CFR461.70) - BPT, BAT, NSPS, PSES, PSNS specified for various processes

 

Batteries are largest source of Hg in MSW incinerators.

In 1996, Congress passed the Mercury-Containing and Rechargeable Battery Management Act which phases out the use of mercury in batteries sold in the U.S. The sole exception are button-cell batteries whose mercury content is limited.

 

 

Instruments And Related Products

Measuring & Control Instruments

 

Use: Hg used to measure or control reactions and equipment functions;

Products: thermometers (primary use), pressure sensing devices (barometers, manometers), navigational equipment, seals, valves; medical/ scientific instruments: Hg emissions occur during cleaning and refilling, and from instruments in municipal solid waste

None

None

 

Digital thermometers are replacing Hg thermometers.

Hg thermometers banned in Sweden.

MN has special management and disposal restrictions on thermostats.

Dental Equipment & Supplies

 

Uses: forms alloys; chemically binds compounds together to form stable restorative material (amalgam is an alloy) Products: dental amalgam -- fillings for teeth, other dental equipment and supplies.

None

No specific pretreatment regulations --POTWs may develop education programs for dental offices

 

Dental amalgams may be a major source of elemental mercury vapor exposure to the general population. Dental amalgam in waste water contributes to POTW Hg levels; may contribute to mercury emissions in crematories.

NOTE: For product-specific information, please see Appendix B. Mercury has several thousand applications. Not all products and uses are specifically listed.

Source

# Fac.
In Gl*

Origin/uses
Of Mercury

Air Releases **

Water
Discharges ***

Waste
Management****

Comments

PRODUCT DISPOSAL - INCINERATION AND LAND DISPOSAL

Municipal Waste Incineration

(under CAA, fuel feed stream must be >30% municipal waste)

 

Hg is present in solid waste (batteries, electric lighting, etc.) - Hg emitted when waste is burned at high temperatures.

EPA has established MACT standards for major stationary sources. Rule compliance date is 12/2000.

MN - proposed waste combustion rules including emissions limits; new incinerator permits with Hg limits will require air monitoring systems and periodic stack testing.

N/A

MSW ash is considered hazardous waste if it exceeds RCRA toxicity levels. Supreme Court decision (Chicago v. EDF, March 1994)

Municipal solid waste includes waste generated from residential, commercial, and institutional sources; equipment installed to trap fly ash and acid rain gases do not control Hg emissions

MN: Hg must be removed from products before disposal. OH: Considering installing Hg emission control equipment and separating Hg containing products; IL: Incinerator technology based on consideration of specific pollutants.

Commercial/ Industrial Waste Incinerators

 

Hg present in wastes: batteries, lighting, etc.

EPA will issue proposed rules by 12/2000, and final rules by 12/2001 in accordance with CAA'129(a)(4).

N/A

   

Sewage Sludge Driers & Incinerators

NY--33
PA--21
MI--19

Hg in sludge from wastewater treatment plants.

CAA - Hg emissions limit = 3200g/24hrs; annual monitoring and reporting if Hg emissions exceed 1600 g/24hrs; prescribed emissions testing procedure or procedures for sludge to demonstrate compliance (40CFR61.52, NESHAPS); Listed as source category for HAP emissions limits (CAA '112(c)(1))

(see wastewater treatment)

 

EPA is considering a revised rule.

Wastewater Treatment

 

Hg present in wastewater entering facility

No existing standards; not listed as category of HAP sources.

Mercury is eligible for removal credits - POTWs may request removal credits against facility pretreatment limits, as long as POTW meets sludge concentration limits

Sludges for land application or surface disposal must meet specific concentration requirements for agricultural land, forest land, public contact sites, home garden application or landfills

Hg concentration limits in sludge: 57 mg/kg limit for land application of sludge (40CFR503)

EPA will conduct studies to characterize HAP emissions from industries discharging to POTWs

Hazardous waste incinerators may test Hg content in sludge in lieu of emissions testing requirements.

Western Lake Superior Sanitary District (WLSSD) in Duluth, MN has active pollution prevention program

MI - POTWs must have waste minimization plans

Hazardous Waste Incinerators

IL--1

No uniform emissions standards; Hg limits depend on individual permits; facilities shielded from regulatory changes until permit expires (CFR 264.344)

Waste analysis required to determine Hg concentrations unless incinerator has documentation of no Hg presence (40CFR265.341)

Rule expected in 1999.

Residues must meet LDR specifications

EPA is revising draft hazardous waste combustion rules based on MACT standards

Cement kilns also burn hazardous waste

Medical Waste Incinerators

 

Hg in wastes generated from hospitals, clinics, labs, etc.

In 1997, EPA set mercury emissions limits based on MACT standards for new and exisiting facilities. Rule Comply date is 9/2002..

WI - incinerators with capacity >5 tons/day must be tested for Hg during first 90 day period and following year

 

 

 

 

 

Landfills

 

Mercury in products in the municipal waste stream, especially those subject to breakage such as thermostats, thermometers, and fluorescent lamps.

Under CAA ('112(d)) EPA will issue mercury emission standards for municipal solid waste landfills by 11/2000. Regulations will be based on MACT standards.

Monitor for Hg in groundwater; leachate testing requirements

Subtitle D (non-hazardous) landfills: leachate cannot exceed 0.2mg/l Hg;

Subtitle C (hazardous waste) landfills: disposal prohibited unless waste undergoes prescribed treatment to reduce Hg to regulated levels

Determine Hg concentrations if food chain crops are grown - Hg cannot be transferred to food chain portion of crop

MN - studying Hg content of landfill gas and leachate. IL - Hg components must be removed from discarded white goods (e.g. appliances) before disposal

MN: Hg must be removed from products before disposal.

Ash disposal facilities

 

Mercury in incinerator ash

permit specific

     

Auto salvage/ scrap yards

 

Automobile components have Hg, some automobiles used for illegal disposal; Hg released from crushing switches

   

MN monitors mercury levels

MN: developing best management practices for yard operators

Crematories

 

Hg in dental fillings volatilizes during cremation

 

Crematorium and pathological unit rules will be proposed 11/1999, as required by CAA '129.

 

 

 

 

 

Hospitals, Dentists

 

Mercury in waste streams (water and solid waste)

 

No pretreatment regs

 

IL: P5 Bureau gives guidance on Hg disposal

MN: WLSSD has a brochure for dentists

OH: Community volunteer efforts address Hg in waste

Source

# Fac.
In Gl*

Origin/uses
Of Mercury

Air Releases **

Water
Discharges ***

Waste
Management****

Comments

MERCURY AS A BY-PRODUCT OF MANUFACTURING PROCESSES 

Carbon Black Production

MI--1
OH--1

Hg present in oil feedstock

 

No Hg limits; but discharge of process waste water prohibited except to POTWs. 40CFR458

 

 

 

Coke Production

IL--3
IN--3
MI--1
NY--1
OH--3, PA--3

Hg is By-product present in coal used as feedstock for coke oven batteries (primary feedstock for iron and coal industry)

 

 

 

 

 

 

 

Petroleum Refining

 

Hg present in petroleum crude

  

No specific Hg limits.

     

Lime Manufacturing

IL--1
OH--1
PA--1

Hg present as impurity in processed stone and from fuel used to heat kilns

 

 

 

 

 

 

 

Portland Cement Manufacturing

 

Hg present in ore and minerals used as raw materials; Hg in fossil fuels used in cement kilns

EPA issues proposed rules in 3/98.

Feed rate screening limits for mercury specified under interim standards for burners or industrial furnaces (40CFR266.103 and 266.106)

 

 

 

Cement kiln dust exempt from RCRA hazardous waste definition.

Cement industry is increasing its use of municipal, industrial, and hazardous wastes for kiln firing to replace fossil fuel use (for energy conservation); EPA is revising draft hazardous waste combustion rules

Phosphate-based fertilizer factories

 

Hg is trace element in rock phosphate

       

Primary Smelting & Refining of Copper

MI--1

Copper recovered from sulfide ore that contains Hg

 

Hg effluent limits for copper, lead, zinc, gold, silver ores subcategory (40 CFR 440.100)

 

Residues exempted from RCRA under Bevill exclusion

Primary Smelting & Refining of Nonferrous Metals, Except Copper & Aluminum

 

Hg present in almost all minerals; lead recovered from sulfide ore that contains Hg; zinc smelting process generates Hg emissions

No existing regulations for mercury

Many mining facilities are listed as source categories for HAPS

Hg effluent limitations for: primary antimony subcategory (nonferrous metals category). (40CFR421.140); copper, lead, zinc, gold, silver, and molymbdnenum ores (40CFR440.100), and platinum ores subcategory (440.110)

 

Residues exempted from RCRA under Bevill exclusion

Source

# Fac.
In Gl*

Origin/uses
Of Mercury

Air Releases **

Water
Discharges ***

Waste
Management****

Comments

MERCURY RELEASED AS A BY-PRODUCT IN POWER GENERATION AND HEATING

Electric Power Generation (Utility Boilers)

 

Hg present in coal, oil, natural gas, or wood used in electric utility steam generating units - emitted as trace contaminant when volatilized at high temperatures.

No current Hg emissions limits under CAA. CAA 112(n)(1)(A) Utility Study Report to Congress (1998) analyzed the public health hazards from utilities; EPA may promulgate regulations based on study results; utilities exempted from list of sources accounting for 90% of Hg emissions that will require MACT standards ('112(c)(6)

No detectable Hg allowed in discharge

Residues exempt from RCRA under Bevill exclusion

Coal has highest Hg content of fossil fuels. 80% of energy consumption in utility boilers is from coal combustion; 95% of coal is bituminous and subbituminous coal.

Commercial & Industrial Boilers

   

Hg present in fuels

EPA will issue proposed rules 12/2000, and final rules 12/2001.

 

 

 

 

 

Residential Boilers and Wood Stoves

  

Hg present in fuels

           
 

Notes:

Source categories used to identify manufacturing uses of mercury follow Bureau of Mines categories, which track U.S. industrial consumption of refined Hg metal.

Mercury releases to air, water and land are reported by manufacturing firms that meet TRI threshold requirements. Manufacturing facilities (SIC codes 20-39) that have 10 or more full time employees and manufacture/process 25,000 pounds of a listed chemical or otherwise use 10,000 pounds of a listed chemical must report chemical release information in TRI. 

*

"# FAC. IN GL" = number of facilities in Great Lakes States.
Source: National Emissions Inventory of Mercury and Mercury Compounds: Interim Final Report, USEPA, 12/93.

**

Air emissions: EPA must list source categories that account for 90% of aggregate Hg emissions by 1995, excluding electric utilities. Sources will be subject to MACT standards within 10 years ('112(c)(6)). EPA has also published a list of major categories and subcategories of sources that emit hazardous air pollutants (including mercury and compounds). Any stationary source emitting more than 10 tons per year of a listed substance or 25 tons per year of any combination of substances will be subject to MACT standards. Major air toxics emitters will require permits.

***

Water discharge: BAT=best available control technology, BPT=best practicable control technology, NSPS=new source performance standards, PSNS=pretreatment standards for new sources, PSES=pretreatment standards for existing sources. States may impose more stringent permit limits to meet water quality standards for mercury (standards vary by state). Facilities must notify POTW of hazardous substances discharged which are not covered by pretreatment standards.

****

Waste management: Mercury is a listed and characteristic waste under RCRA. Any source listed here may be generating D009, the RCRA hazardous waste code that identifies wastes characteristic for mercury. Other RCRA waste codes that identify mercury include U151 (mercury), K071 and K106 (listed for mercury) , F039 (listed for multiple sources), P065 and P092 (mercury compounds). All mercury-containing wastes have land disposal restrictions. Specified treatment for mercury-containing wastes is incineration or thermal processing (40CFR 268.42).

 

 

Appendix C:
Regulations on Products that Contain Mercury

Note: This table highlights regulations that affect the most common mercury-containing products. It is not a comprehensive list of all products that may contain mercury. 
The "Comments" section includes general information that expands on the regulatory information.

Product/Use

Role of Mercury

Regulations/Programs on Mercury Products

Fed/State Regulation

Comments

Chemical and Allied Products

 

 

Agricultural Products

Mercury compounds used as pesticides, bactericides, disinfectants, fungicide

Restricted and/or banned under FIFRA

Federal

 

Turf Products

Pesticide

Calo-chlor and calo-gran, the last mercury-based pesticides registered for use in U.S. voluntarily canceled by manufacturer (Grace Sierra Crop Protection) in November 1993

Federal

Approximately 21,000 pounds used annually on golf course turf and greens to control fungi Pink Snow Mold and Grey Snow Mold; manufacturer may sell and distribute products labeled for release or shipment before 6/93 until 6/94: retailers may sell products until stocks exhausted; users may use products until stocks depleted.

Fungicide

Prohibits use of mercury in fungicides

MN

 

Paint

Mercury compounds used as biocide to control microbial growth in paint cans and prevent mildew on painted surfaces

Registrations for mercury compounds in indoor and outdoor latex paint banned or canceled (1990, 1991)

Federal

Manufacturers may use up existing stocks

Cancellation of biocide registrations has reduced Hg consumption in paint, and paint residue in municipal solid waste; paint cans w/mercury residue are still discarded

  

Anti-fouling paints for marine use banned in 1972

Federal

 
  

No Hg deliberately introduced into paint intended for use in MN (except in art supplies)

MN

 

Pigment, Dyes

Coloring (maroon, red, orange) primarily for plastics

Cadmium-mercury pigments no longer manufactured in U.S. (domestic production ceased in 1988); may still be imported

Federal

Many states have laws that phase out metals in pigments

  

No Hg deliberately introduced into pigments and dyes intended for use in MN (except in art supplies)

MN

 

Cosmetics

Preservative, antimicrobial

Limited to eye area cosmetics or ointments with concentration <65 ppm (21CFR700.13)

Federal

 

Pharmaceuticals

Used in antiseptics, ointments, diuretics

Misbranded drug laws - list quantity of mercury in product

IL, IN, NY, OH, PA

 
  

Yellow mercuric oxide is not generally recognized as safe and effective, or is misbranded for over the counter use

Federal

 

Poisons

  

Restrictions on sale of mercury and mercury compounds

OH

 

  

Levels established for Hg products to be considered poisons

PA

 

Catalysts

Hg used as catalysts for production of vinyl chloride monomers and urethane foams, as well as other products

   

Packaging

 

Restrictions on merc contains intentionally introduced Hg content in packaging and packaging components; no products may be sold in packaging that contains intentionally introduced mercury.

FL, IL, MN, NJ, NY, WI

Implementation dates vary by state, and include general exceptions if no feasible alternatives exist; Pennsylvania is considering bill to regulate toxic materials in packaging

Special Paper Coatings

Mercury bromide and mercury acetic acid used in specialized paper and film with cathode ray tubes

   

Manufacturers plan to phase out use of mercury in coating

Explosives

Mercury fulminate is detonator

Explosives containing mercury are Class A, maximum hazards

MN, WI

In the last 20 years, only the military has used mercury explosives

Fireworks

Catalyst/explosive

Permits required for fireworks with mercury

MN

 
 

Fireworks containing mercury are prohibited.

MI, NJ

 

Livestock and Poultry Remedies

 

List percentage of mercury on remedy

MI

 

Product/Use

Role of Mercury

Regulations/Programs on Mercury Products

Fed/State Regulation

Comments

Electrical and Electronic Uses

   

Electric Lighting

   

Electric lighting products are second largest component of municipal solid waste (after batteries)

Fluorescent Lamps
(low pressure)

Mercury vapor fluoresces at UV wavelength

Encouraged as replacement for incandescent bulbs for energy conservation (see 10CFR450.31 - energy conservation measures). Included in the Universal Waste Rule.

Federal

Fluorescent lights are largest component of electric lighting discards in municipal solid waste; used bulbs considered hazardous waste because high levels of mercury exceed RCRA toxicity

  

Lamps in state-owned buildings must be recycled.

MN

characteristic limit (.2 mg/l in leachate)

  

Viewed as by-product that can be recycled, and exempt from RCRA

OH

  
  

Lamps sold to managers of industrial, commercial, office, or multi-unit buildings must be labeled; building contractors must specify mercury management plans for removed lamps

MN

  
  

Lamps containing mercury must be labeled.

VT

  

Mercury Vapor Lamps

 

Facilitates light production by electric arc

Encouraged for energy conservation (see 10CFR450.31 - energy conservation measures) Included in the Universal Waste Rule.

Federal

  
  

Lamps must be self-extinguishing or have protective shield; efficiency standards in public areas (theaters, gyms)

NY

   
  

Mercury must be removed before disposal; lamp sellers and contractors responsible for public education about mercury management requirements; limits on production and distribution of lamps

MN

   

  

Lamps containing mercury must be labeled.

VT

  

High Intensity Lamps

 

  

Included in the Universal Waste Rule.

Federal

   
  

Lamps sold to managers of industrial, commercial, offices, or multi-unit buildings must be labeled; building contractors must specify mercury management plans for removed lamps

MN

Used for outdoor lighting; mercury lamps are more efficient and brighter than other outdoor lights

  

Lamps containing mercury must be labeled.

VT

  

Metal Halide Lamps

  

Included in the Universal Waste Rule.

Federal

Encouraged for energy conservation (see 10CFR450.31- energy conservation measures)

  

Lamps containing mercury must be labeled.

VT

  

Incandescent Lamp Filaments

Hg used as continuous electrical contact in tungsten bar sintering

Included in the Universal Waste Rule.

Federal

  
  

Lamps containing mercury must be labeled.

VT

  

Product/Use

Role of Mercury

Regulations/Programs on Mercury Products

Fed/State Regulation

Comments

Wiring Devices and Switches

   

Thermostats

Temperature measurement

Mercury must be removed for recycling or recovery before disposal; manufacturers must provide information and incentives to ensure recycling or proper management; heating, ventilating and air-conditioning (HVAC) dealers required to properly manage or recycle used mercury thermostats (MN St 115A.93, 115A.9561, 115.932)

MN

Digital thermostats are replacing mercury thermostats; long lag time before old Hg thermostats discarded

  

Products containing Hg must be labeled, including disposal restrictions

MN

MN has pilot program for HVAC dealers to recycle mercury containing thermostats by returning them to HVAC wholesaler who, in turn, returns them to Honeywell for recycling/reclaiming

White Goods

Mercury components (e.g., switches) may be included in large appliances (e.g., refrigerators, air conditioners, etc.)

Mercury components must be removed prior to disposal

MN, IL

   

  

Hg in repaired or replaced items must be reused or recycled

MN

  

Toys

   

Ban on toys with Hg; fines imposed for retail sales

MN, WI

   

Electric Wall Switches

  

Products containing Hg must be labeled, including disposal restrictions

MN

  

Electrical Components

May be included in any electrical machinery (e.g., mining, automotive, and industrial equipment, smoke detectors, etc.)

Limits on mercury use in mining equipment

PA

  
    

Products containing mercury must be labeled, including disposal restrictions

MN

  

Product/Use

Role of Mercury

Regulations/Programs on Mercury Products

Fed/State Regulation

Comments

Batteries

           

General Mercury Containing Batteries

  

Batteries included in universal waste rule to ease RCRA restrictions on hazardous waste management and divert waste from MSW landfills; states may set up special collection programs not subject to storage, transportation, and permitting requirements of RCRA 1996 Battery Management Act bans all mercury-containing batteries in the U.S., except for button-cells batteries.

Federal

Batteries were largest source of Hg in municipal solid waste. Many states have banned mercury in batteries; manufacturers have reduced mercury use by over 90% since 1988.

EPA is requesting comments on labeling batteries to aid in collection, sorting, and recycling; denied a petition filed under 'TSCA to require deposit on mercury-containing batteries.

 

Deposit/refund system will begin in 1998: purchasers return used mercury batteries to retailer or approved collection facility

MI

 
 

Task force on storage, transport, disposal, recycling

IL

Industry groups have developed uniform voluntary industry labeling standards for lead and cadmium batteries

Alkaline Batteries

 

 

Prevents corrosion and hydrogen release, extends shelf life; improves performance over temperature range (batteries used in flashlights, radios, and other electronics)

Hg concentrations <.025% by weight

MN, NY

Battery manufacturers have eliminated mercury in alkaline batteries, except button cells and reusable batteries.

  

Hg banned in alkaline batteries in 1996

MN, WI

  

  

  

MN

  

Mercuric Oxide Batteries (also button cell, mercury-zinc button cell)

Mercury used as cathode material and is integral component (button cell batteries contain ~40% mercury)

Sale of dry cell batteries with mercuric oxide, electrode batteries prohibited without exemption; button cell nonrechargeable batteries restricted to <25mg Hg; labeling requirements; disposal prohibited; manufacturers responsible for collection system

MN

Primarily used in hearing aids; also used in calculators, watches, cameras, photographic equipment, electronic games, health/hospital equipment, airplane underwater locator beacons

  

Hg content of alkaline button cell batteries must be <25 mg by weight

NY

NY is exploring recycling options for these batteries

        

Some mercuric oxide cells used in military and medical operations (e.g., night vision devices, EKG machines, etc.) are disposed of as hazardous waste. Proposed federal legislation may ban mercuric oxide batteries.

Carbon Zinc (LeClanche)

Contain ~1% Hg; Hg controls chemical reactions between zinc and other battery components

Sale prohibited if Hg concentration >1ppm

NY

Carbon zinc cells have shorter life than alkaline batteries. Mercury is no longer used in certain zinc battery products.

   

Sale of batteries with Hg banned after 1994

WI

   

Zinc Air

Hg content ~ 1%

Button cells restricted to <25 mg mercury, labeling

MN

Used in pagers, hearing aids

Product/Use

Role of Mercury

Regulations/Programs on Mercury Products

Fed/State Regulation

Comments

Instruments and Related Products

     

Measure and Control Instruments

     

Thermometers

Elemental mercury indicates temperature

Limits on distribution of Hg thermometers; mercury must be removed before disposal; no routine distribution of Hg thermometers by medical facilities

MN

Digital thermometers are replacing mercury thermometers

Barometers

Indicates pressure

  

  

Medical, Scientific Instruments

Temperature and pressure measuring devices

Products w/Hg must be labeled, including disposal restrictions

MN

  

Dental Equipment and Supplies

     

Dental Equipment/ Supplies

Forms alloys; chemically binds compounds to form restorative material

FDA regulates dental mercury and amalgam alloys separately as class I and class II devices under Federal Food, Drug, and Cosmetic Act

Federal

One of nation's largest manufacturers of mercury amalgam dental fillings will place warnings on amalgam containers shipped to California and provide warning signs for dental patient waiting rooms under California's Proposition 65 (Safe Drinking Water and Toxic Enforcement Act).

  

Disposal banned unless mercury reused, recycled or managed to ensure compliance

MN

 
  

Purchaser must sign agreement of use for medical or dental uses

MN

The Act requires businesses that use or distribute toxics to label or otherwise notify the public about possible exposure to chemicals.

Discontinued Uses

           

embalming fluid

Preservative

  

  

film pack batteries

  

Use discontinued as of 1988

    

maritime paints

Antifouling agent

Registrations suspended in 1972

Federal

    

photographic development

 

  

soap

  

  

  

  

wood preservatives

  

  

  

 

 

Appendix D:
Examples of State Mercury Controls

Adapted from the Mercury Study Report to Congress Volume VIII, 1997

 

Mercury Sources/targets

States with Controls

Control/action

ENVIRONMENTAL SOURCES

General

 

Minnesota

State has established goals of reducing total mercury releases, from new and existing sources, into air and water by 60 percent from 1990 levels by 12/31/2000, and by 70 percent from 1990 levels by 12/31/2005.

Vermont

State has established an advisory committee on mercury pollution.

Air Point Sources

 

 

 

Florida

Mercury emission standard for municipal solid waste incinerators (65 micrograms/m3).

Maine

An air emission source may not emit mercury in excess of 100 pounds per year after January 1, 2000, and 50 pounds per year after January 1, 2004.

Minnesota

Proposed waste combustion rules include emission limits.

New incinerator permits with mercury limits will require air monitoring systems and periodic stack testing.

New Jersey

Mercury emission standard for municipal solid waste incinerators (65 micrograms/m3), with further reductions to be phased in.

Ohio

Considering installing mercury-emission control equipment.

Wisconsin

State will prepare and adopt minimum standards for mercury air emissions.

Medical waste incinerators with capacity greater than 5 tons per day must be tested for mercury during the first 90 day period of operation and once the following year.

Water Point Sources

 

 

 

Maine

After January 1, 2000 mercury dischargers in water from industrial facilities must be less than 1 pound per year, and after January 1, 2002 must be less than 0.1 pound per year.

Department of Environmental Protection has proposed, "Chapter 519, Interim Effluent Limitation and Controls for the Discharge of Mercury" under 38 MRSA Section 420 and Chapter 500, Public Laws of 1999.  This rule will require discharge sources to implement pollution prevention plans following models prepared by the Department, and may require progress reports.  Dischargers of municipal wastes, industrial process wastes and other similar sources will be subject to testing requirements and interim effluents for mercury.  Based on these tests the Department will establish both average and daily maximum limits.

Michigan

Businesses must report use and discharge information for mercury under the Water Pollution Control Act.

Wisconsin

State will adopt maximum discharge limits on mercury and mercury compounds.

Hg-Containing Wastes

 

Florida

It is illegal for small quantity generators (SQGs) to knowingly place batteries or products containing a mercuric oxide electrode into their solid waste stream. Also, manufacturers and distributors of mercuric oxide batteries are required to implement a take-back program for these batteries and products with non-removable batteries, without regard to brand.

The incineration of, or landfill disposal of mercury-containing devices and spent lamps is prohibited.

Requires local governments to implement source separation programs at solid waste facilities to remove mercury containing devices.

Minnesota

Management standards for facilities recycling mercury- containing hazardous wastes (currently being drafted).

Mercury must be removed from products before disposal.

New Hampshire

Established a committee to study mercury source reduction and recycling issues.

Vermont

Labeled mercury-added consumer products must be separated and disposed of in authorized facilities.

All solid waste districts and municipalities must implement public information and mercury-collection programs.

State prohibits landfill disposal of labeled mercury-added consumer products.

Wisconsin

State requires testing and reporting of mercury emissions by operators of Medical Waste Incinerators.

Mercury Sources/targets

States with Controls

Control/action

PRODUCTS

White Goods

Illinois

Mercury components must be removed from discarded white goods before disposal.

Minnesota

Products containing mercury must be labeled, and the labels must include any disposal restrictions.

Mercury components must be removed prior to disposal.

The distribution of mercury- containing fever thermometers is restricted.

Manufacturers must provide information and incentives regarding recycling or proper management.

HVAC dealers are required to properly manage or recycle used mercury thermostats.

Mercury in repaired or replaced items must be recycled.

Batteries

 

 

 

Arkansas

Ban on the manufacture of alkaline batteries containing any mercury effective 1- 1- 96.

Ban on the manufacture of mercury- containing zinc carbon and mercury button cell batteries effective 1- 1- 94.

State issued regulations defining collection procedures and responsibilities of the manufacturer and user of mercury batteries effective 1- 1- 94.

California

Required manufacturer to reduce the level of mercury to 0.025% by weight in alkaline batteries effective 1- 1- 94, and ban on the manufacture of alkaline batteries containing any mercury effective 1- 1-96.

Ban on the manufacture of mercury- containing zinc carbon and mercury button cell batteries effective 1- 1- 94.

Connecticut

Required manufacturer to reduce the level of mercury to 0.025% by weight in alkaline batteries effective 1- 1- 92.

Ban on the manufacture of mercury- containing zinc carbon batteries effective 1- 1- 93.

Collection of mercury button cell batteries required by retailer effective 1- 1- 92.

State issued regulations defining responsibilities of manufacturer, supplier and user effective 1- 1- 92.

Florida

Ban on the sale of alkaline batteries containing mercury greater than 0.025% by weight effective 7- 1- 95, and ban on the retail sale of alkaline and zinc carbon batteries containing any mercury effective 1- 1- 96.

Ban on the sale of mercury button cell batteries effective 10- 1- 93.

State issued regulations defining collection procedures and responsibilities of the manufacturer and user of mercury batteries effective 1- 1- 94.

Ban on the sale of mercury containing batteries if manufacturer fails to meet collection procedures and other responsibilities effective 1- 1- 94.

Illinois

Task force to study storage, transport, disposal and recycling.

Iowa

Ban on the sale of alkaline batteries containing mercury greater than 0.025% by weight effective 7- 1- 93, and ban on the retail sale of alkaline batteries containing any mercury effective 1- 1- 96.

State issued regulations defining responsibilities of manufacturer, supplier and user effective 7- 1- 96.

Ban on the sale of mercury- containing batteries (including button cells) if manufacturer fails to meet collection procedures and other responsibilities effective 7- 1- 96.

Collection of mercury button cell batteries required by retailer effective 7- 1- 96.

Maine

Ban on the sale of alkaline batteries containing mercury greater than 0.025% by weight effective 1- 1- 94, and ban on the manufacture of alkaline batteries containing any mercury effective 1- 1- 96.

Ban on the sale of mercury containing zinc carbon batteries and mercury button cell batteries effective 1- 1- 93.

State issued regulations defining collection procedures and responsibilities of the manufacturer and user of mercury batteries effective 1- 1- 94.

Maryland

Collection of mercury button cell batteries required by retailer effective 7- 1- 94.

Ban on the sale of mercury button cell batteries if manufacturer fails to meet collection, transportation, disposal and consumer education responsibilities effective 7- 1- 94.

General ban on the sale of mercury containing batteries effective 7- 1- 94, but state authorized to grant exemptions if certain requirements are met.

State issued regulations defining responsibilities of manufacturer, supplier and user effective 7- 1- 94.

Massachusetts

Ban on the retail sale of mercury- containing alkaline batteries effective 1- 1- 95 is pending.

State regulations defining collection procedures and responsibilities of the manufacturer and user of mercury batteries are pending.

Ban on the sale of mercury button cell batteries is pending.

Michigan

A new battery law signed on June 29, 1995.

This law bans the sale of alkaline batteries containing mercury (with the exception of alkaline manganese button cells containing less than 25 mg of mercury) and zinc carbon batteries containing mercury beginning January 1, 1996.

The sale of mercuric oxide batteries (with the exception of button cells) are also banned for sale after January 1, 1996, unless the manufacturer identifies a collection site for recycling, informs users of the locations and informs the purchasers of a telephone number that can be called to get information about returning mercuric oxide batteries for recycling or proper disposal.

Minnesota

Required manufacturer to sell alkaline batteries containing no more than 0.025% mercury by weight effective 2- 1- 92, and has banned manufacturer sale of alkaline batteries containing any mercury effective 1- 1- 96.

General ban on the sale of mercury- containing batteries effective 2- 1- 92, but state authorized to grant exemptions if certain requirements are met.

Mercury batteries may not contain more than 25 mg of mercury unless an exemption is granted.

Sale of dry cell batteries with mercuric oxide and electrode batteries prohibited without exemption.

Ban on mercury button cell batteries effective 2- 1- 92.

Manufacturers must set up collection, transport, recycling and consumer education programs.

New Hampshire

Required manufacturer to reduce the level of mercury in alkaline batteries to 0.025% by weight effective 1- 1- 93, and has banned the manufacturer sale of alkaline batteries containing any mercury effective 1- 1- 96.

Ban on the manufacture of mercury- containing zinc carbon batteries effective 1- 1- 93.

State issued regulations defining collection procedures and responsibilities of the manufacturer and user of mercury batteries effective 1- 1- 93.

State issued regulations regarding the collection of mercury button cell batteries effective 1- 1- 93.

New Jersey

Required manufacturer to reduce the level of mercury to 0.025% by weight in alkaline batteries effective 1- 1- 92, and ban on the manufacture of alkaline batteries containing any mercury effective 1- 1-96.

Ban on the manufacture of mercury- containing zinc carbon batteries effective 1- 1- 92.

Ban on mercury button cell batteries effective 1- 1- 94.

State issued regulations defining collection procedures and responsibilities of the manufacturer and user of mercury batteries effective 1- 20- 93.

Sale of mercury batteries banned if manufacturer fails to meet collection and other responsibilities effective 1- 20- 93.

New York

Required manufacturer to reduce the level of mercury to 0.025% by weight in alkaline batteries effective 1- 1- 92.

Ban on the manufacture of mercury- containing zinc carbon batteries effective 1- 1- 93.

Mercury oxide battery ban pending.

Oregon

Required manufacturer to reduce the level of mercury to 0.025% by weight in alkaline batteries effective 1- 1- 92.

Rhode Island

Required manufacturer to reduce the level of mercury to 0.025% by weight in alkaline batteries effective 1- 1- 92.

State issued regulations defining collection procedures and responsibilities of the manufacturer and user of mercury batteries effective 1- 1- 94.

Ban on mercury button cell batteries effective 1- 1- 93.

Vermont

Required manufacturer to reduce the level of mercury in alkaline batteries by 0.025% by weight effective 2- 1- 92, and ban on the retail sale of alkaline batteries containing any mercury effective 1- 1- 96.

Ban on mercury button cell batteries effective 1- 1- 93.

State issued regulations defining collection procedures and responsibilities of the manufacturer and user of mercury batteries effective 1- 1- 93.

Batteries sold to the public containing mercury must be labeled, other than button batteries.

Wisconsin

Ban on the manufacture of mercury- containing alkaline batteries effective 1- 1- 96, and ban on the manufacture of mercury- containing zinc carbon batteries effective 7- 1- 94.

State issued regulations defining collection procedures and responsibilities of the manufacturer and user of mercury batteries effective 7- 1- 94.

Ban on the manufacture of mercury- containing batteries if manufacturer fails to meet collection procedures and other responsibilities effective 7- 1- 94.

Mercury Sources/targets

States with Controls

Control/action

Electrical Components

Minnesota

Switches, electric relays, or other electrical devices individually or as part of another product, that contain mercury, must be labeled, and the labels must include any disposal restrictions.

Pennsylvania

Mercury use in mining equipment (i.e., electrical machinery) is limited.

Vermont

Requires labeling of switches, electric relays, or other electrical devices individually or as part of another product, that contain mercury.

Paints and Pigments

Minnesota

No mercury can be deliberately introduced into products intended for use in Minnesota, except for art supplies.

Medical and Dental Uses

 

Minnesota

Disposal of dental equipment and supplies containing mercury is banned, unless the mercury is reused, recycled, or managed to ensure compliance.

Purchaser must sign an agreement of use for medical or dental uses.

Ban on the use of mercury manometers.

New Jersey

New Hampshire

Prohibits sale or use of embalming fluids containing mercury.

Vermont

Products containing mercury must be labeled.

Toys

 

Michigan

No sale of toys containing mercury (pending).

Minnesota

Toys with mercury are banned and fines are imposed on retail sales of toys containing mercury.

Wisconsin

Laboratory Uses

Michigan

Mercury will be banned in school labs by the year 2000.

Lighting

 

Florida

Ban on incineration of lamps. Crushing, landfilling and recycling of lamps allowed with appropriate controls (proposed).

Florida also will control management of residual mercury from recycling operations.

Minnesota

Fluorescent lamps and high intensity lamps sold to managers of industrial, commercial, office, or multi-unit buildings must be labeled and building contractors must specify mercury management plans for removed lamps.

Lamps in state- owned buildings must be recycled.

Mercury must be removed from mercury vapor lights before disposal and lamp sellers and contractors must provide public education about mercury management requirements.

The production and distribution of mercury vapor lights are limited.

New York

Mercury vapor lights must be self- extinguishing or have protective shield.

Ohio

Lamps are viewed as by- products that can be recycled, and exempt from RCRA.

Vermont

Lamps containing mercury must be labeled.

Poisons

Ohio

The sale of mercury and mercury compounds is restricted.

Pennsylvania

Levels established for mercury products considered to be safe.

Packaging

Florida

State bans the sale of, and restricts the use of packaging and packaging components containing mercury.

New Jersey

 

Illinois

Minnesota

New York

Wisconsin

Restrictions on mercury content in packaging are being phased in. (Dates and concentrations vary by state).

Pharmaceuticals

Michigan

Labeling of livestock remedies containing mercury is required.

Illinois

Indiana

New York

Ohio

Pennsylvania

Manufacturers must list the quantity of mercury in products.

Explosives/Fireworks

 

Michigan

The sale or use of fireworks containing mercury is prohibited.

New Jersey

 

Minnesota

Explosives containing mercury are Class A maximum hazards.

Wisconsin

Permits required for fireworks with mercury (Minnesota only).

Thermostats and Thermometers

 

Minnesota

Manufacturers of thermostats containing mercury must label such items and provide incentives for, and information to, purchasers and consumers to ensure the mercury disposal is properly managed. Otherwise, the manufacturer is liable for improper disposal of such thermostats by purchasers and consumers.

Medical facilities may not routinely distribute thermometers containing mercury.

Vermont

Products containing mercury must be labeled.

Automobiles

Minnesota

Crushing of automobiles is prohibited unless a good faith effort has been made to remove all mercury switches.

 

 

Appendix E:
Federal Mercury Controls

Adapted from OECD, 1995

Specific Sources/focus

Control/action

ENVIRONMENTAL MEDIA

Drinking Water

Maximum contaminant level (MCL) = 0.002 mg/ L (40 CFR 141.62, 21 CFR 103.35).

Surface Water

Ambient Water Quality Criteria; water and organisms = 0.012 μg/ L (40 CFR 401, 403, Appendix B).

Water Quality Guidance for the Great Lakes System: aquatic life = 1.44 μg/ L (acute) and 0.77 μg/ L (chronic);

human health = 0.0018 μg/ L; wildlife = 0.0013 μg/ L (40 CFR 132).

Air

No ambient air standard.

Soil

No soil standard.

ENVIRONMENTAL SOURCES

Air Point Sources

Emissions from mercury ore processing facilities and mercury cell chlor- alkali plants are limited to a maximum of 2,300 g/ 24 hours (40 CFR 61.01).

Emissions from sludge incineration plants, sludge drying plants, or a combination of these that process wastewater treatment plant sludges are limited to a maximum of 3,200 g/ 24 hours (40 CFR 61.52).

Industrial sources emitting mercury and mercury compounds may be subject to Maximum Achievable Control Technology (MACT) standards for major stationary sources and Generally Available Control Technology (GACT) standards for area sourcesb.

Emission guidelines on mercury emissions from municipal waste combustors under '' 111 and 129 of the 1990 Clean Air Act Amendments.

Regulations on mercury emissions from medical waste incinerators under '' 111 and 129 of the 1990 Clean Air Act Amendments were promulgated on August 15, 1997.

Airborne emissions of mercury on and other substances from the burning of hazardous waste in boilers and industrial furnaces, including cement kilns, are regulated under the Resource Conservation and Recovery Act (40 CFR 266).

Water Point Sources

Effluents from industrial facilities and municipal wastewater treatment facilities are regulated through industry- specific pretreatment standards and effluent guidelines for existing and new sources of pollution and are based on the limits of theavailable control technology (40 CFR 401, 403, Appendix B).

Groundwater at hazardous waste treatment, storage and disposal facilities must be monitored for the presence of mercury (40 CFR 302.4, 264.94).

Sewage Sludge

Permissible levels of mercury in municipal wastewater treatment sludges: 17 mg/ kg dry wt. and cumulative load of 17 kg/ hectare for agricultural land; 17 mg/ kg dry wt. and annual load of 0.85 kg/ hectare for home garden or lawn; 57 mg/ kg dry wt. for other land applications; and 100 kg/ hectare for surface disposal (CWA).

Mercury-Containing Wastes

Any solid waste (including soil that is being disposed) is considered a hazardous substance and prohibited from disposal in RCRA Subtitle D (non- hazardous) landfills if its leachate contains 0.2 mg/ L mercury or greater (40 CFR 261.24); land disposal in RCRA Subtitle C (hazardous) landfills is allowed only after prescribed treatment to reduce mercury in extract to 0.2 mg/ L (40 CFR 268).

Certain wastes are listed as hazardous due, at least in part, to the presence of mercury (e. g., K071 = brine purification muds from the mercury cell process in chlorine production, and K106 = wastewater treatment sludge from the mercury cell process in chlorine production).

The amount of mercury in a number of hazardous wastewaters (e. g., F039, K071, K106, P065, P092) must be treated down to specified levels to meet the land disposal restrictions.

Any Environmental Release

Any release of 1 pound or more of mercury into the environment in a 24- hour period (the reportable quantity) must be reported immediately to the National Response Center if the release is not federally permitted (40 CFR 302).

Certain facilities that release more than a reportable quantity of mercury must immediately report the release to state and local entities.

Any release or transfer of mercury by facilities that exceed use or manufacturing thresholds is reportable under the Toxic Release Inventory.

Foodstuffs or Feed

Action level for methylmercury in fish, shellfish and other aquatic animals = 1 ppm (FDA CPG 7180.07).

The import of foods containing the residue of mercury- containing pesticides that are not registered for use in the U. S. is prohibited.

Specific Sources/focus

Control/action

PRODUCTS

Batteries

By early 1991, all U. S. manufacturers converted production so that the mercury content of batteries, except in button and coincells, did not exceed 0.025% by weight.

Federal legislation pending concerning the manufacture of only "non- mercury" formula batteries of all types by 1- 1- 97.

Federal ban on mercury button cell batteries pending as of 1- 1- 95.

Federal legislation permitting only the manufacture of "no mercury" formula zinc carbon batteries pending as of 1- 1- 95.

Paints and Pigments

All uses of mercury in paints have been discontinued.

Dental Uses

Dental mercury is classified as a Class I medical device, with extensive safety regulations on its use. Dental amalgam alloy is classified as a Class II device, subject to additional special controls.

U. S. Public Health Service has recently studied risks from mercury amalgams and recommended tighter controls on dental uses of mercury and further research to reach more definitive conclusions on risk.

Lighting

Because many fluorescent lamps are classified as RCRA hazardous wastes under current test procedures, U. S. EPA is evaluating options for lamp disposal. Major options are 1) conditional exclusion of lamps from hazardous waste management requirements, and 2) handling lamps in a special collection system for other "low grade" and small quantity hazardous wastes (such as batteries and household pesticides).

Pesticides

No current production of mercury- containing pesticides; all former registrations have been cancelled or requests for voluntary cancellation have been received.

Special Paper Coatings

The only two companies that manufacture these products have announced that plans are being developed to phase out the use of mercury in the coatings.

It is predicted that mercury will be eliminated entirely from this application by 1995.

Pharmaceuticals

Removal or restriction of mercury in "over- the- counter" (OTC) drugs such as anorectal products and topical antiseptics.

Request for additional data on other OTC mercury antimicrobials.

Cosmetics

The use of mercury as a preservative or antimicrobial is limited to eye- area cosmetics or ointments in concentrations less than 60ppm (21 CFR 700.13).

OTHER STANDARDS AND PROGRAMS

Occupational Standards

OSHA Standards: ceiling limit of 0.1 mg/m3 for inorganic and elemental mercury, 0.01 mg/m3 as an 8- hr time weighted average for alkylmercury compounds, and a ceiling limit of 0.04 mg/m3 for alkylmercury compounds.

All forms of mercury are assigned a skin notation, indicating that the substance is absorbed through the skin and therefore skin contact should be avoided.

As an OSHA hazardous chemical, the presence of mercury at a facility requires submittal of a Material Safety Data Sheet.

Transportation Standards

Designated as hazardous substances by the Department of Transportation and subject to requirements for packaging, shipping and transportation (40 CFR 172.101).

Virtual Elimination Project

U. S. EPA and other mercury stakeholders are looking holistically at mercury sources and policies to identify and promote "cleaner, cheaper, smarter" ways of reducing mercury levels in the Great Lakes region.

Efforts are designed to (1) reduce uses at the source through pollution prevention measures, (2) reduce releases through treatment or other management techniques and (3) clean up sites of past contamination.

 

 

Appendix F:
Voluntary Initiatives

This table is adapted from U.S. Status Report on Mercury, 1999

 

Title

Description

A. Federal Voluntary Partnerships and Initiatives

 

Three northwest Indiana steel mills, Bethlehem Steel Burns Harbor, Ispat Inland Inc. Indiana Harbor Works, and U.S. Steel Gary Works, signed a voluntary agreement with the Lake Michigan Forum, U.S. Environmental Protection Agency (EPA), and the Indiana Department of Environmental Management (IDEM), on September 15, 1998, to reduce the use of mercury at their facilities. The mills intend to develop a clean sweep/pollution prevention initiative to inventory, recycle, and substitute to the greatest extent practicable mercury at their facilities.

 

EPA and the American Hospital Association (AHA) signed a memorandum of understanding, on June 25, 1998, committing them to work together to significantly cut hospital wastes by 2005. The agreement envisions the virtual elimination of mercury-containing hospital wastes and a one-third reduction in total hospital wastes by 2005. EPA and AHA intend to co-sponsor a series of national waste management seminars for hospitals. The agreement also covers: obtaining and reviewing industry information on pollution prevention efforts; developing model plans for cutting chemical wastes; and investigating pollution prevention opportunities for ethylene oxide and persistent, bioaccumulative, and toxic pollutants.

 

EPA Region 5 recently awarded a matching funds grant to the Ecology Center of Ann Arbor, to promote pollution prevention (P2) in the health care industry in partnership with the Michigan Hospital Association. The project will focus on mercury reduction in SE Michigan. The award was made through the Environmental Justice P2 Grant program competition.

 

The Chlorine Institute has provided to USEPA its first annual report detailing the chlor-alkali industry's progress towards meeting a voluntary commitment to reducing mercury use 50 percent by 2005. The report includes descriptions of activities undertaken to help identify reduction opportunities, and also provides data on preliminary reductions achieved in 1996 and 1997. The Chlorine Institute's report can be viewed at: http://www.epa.gov/bns/bnsmerc.html

 

Olin Corp. has set a goal to eliminate discharges of mercury used to produce chlorine and caustic soda at its two chlor-alkali plants. The company will be involved in a research program designed to answer uncertainties about the quantity of mercury released from these plants. The research will be conducted by the Department of Energy's Oak Ridge National Laboratory, and the Universities of Tennessee and Michigan, and will be funded by Olin Corp., and EPA.

 

EPA=s Green Lights Program is a voluntary initiative with state and local governments, and industry, that encourages use of high efficiency light fixtures and use of appropriate disposal/ recycling for mercury containing lamps.

Title

Description

B. State Voluntary Partnerships and Initiatives

 

Wisconsin Department of Natural Resources provided information encouraging mercury reduction to state hospitals and clinics in 1998. A booklet, AMercury-Free: What=s In It for Me@, was included with the annual medical waste report that hospitals must complete for the state. This outreach effort was the result of interaction and cooperation between two different bureaus within DNR. While hospitals are not required to report on mercury reduction efforts underway, two chose to do so.

 

Wisconsin Department of National Resources is partnering with electric utilities through the Thermostat Recycling Corporation (TRC), community clean sweeps, household hazardous waste collection facilities, and other means to promote recycling and replacement of mercury-switch thermostats. Two of the state=s six major utilities have included promotional materials with customer bills and/or on their web sites. TRC reports that, since November 1997, 932 thermostats have been collected; 69 recycling bins have been issued; and 9.7 pounds of mercury have been reclaimed.

 

Beginning in the Fall of 1998, the Wisconsin Department of Natural Resources, the University of Wisconsin, and the University of Wisconsin Extension Program began replacing mercury-containing manometers to Wisconsin farmers in the Great Lakes basin. This program is funded by a grant from the U.S. EPA Great Lakes National Program Office and is patterned after a similar program in Minnesota.

 

Indiana=s Department of Environmental Management (IDEM) Mercury Awareness Program is a state and local partnership dedicated to investigating and identifying commercial uses of mercury, researching potential pollution prevention options, and developing and implementing outreach strategies for significant sources. In October 1998, IDEM initiated a statewide effort to collect and recycle household items containing mercury. The effort will be led by the Regional Household Hazardous Waste Task Force, a consortium of 35 southern Indiana solid waste management districts, and will involve other solid waste management districts and communities.

 

Michigan=s Mercury Pollution Prevention (M2P2) Task Force was convened in August 1994 and, since that time has been active in numerous mercury pollution prevention efforts across Michigan. A few of the Task Force=s efforts include:

  • Michigan Department of Environmental Quality (MDEQ) has funded a household hazardous waste collection program in 22 counties across Michigan and approximately 200 pounds of mercury have been collected;

  • M2P2 Task Force=s Automobile Subgroup identified 23 uses of mercury in automobiles; and

  • Outreach materials describing mercury threats and disposal options have been distributed to science teachers.

 

In order to evaluate progress towards the zero discharge goal in the Lake Superior basin, baseline information is needed on indicators of releases of nine designated chemicals. The Minnesota Pollution Control Agency (MPCA) is working on two projects to 1) establish a baseline for five mercury indicators and 2) encourage the use of low mercury feedstock chemicals, such as caustic soda. MPCA is also working with a group of Minnesota stakeholders in the development of a comprehensive mercury reduction strategy. The stakeholders are involved through an advisory council that will provide recommendations to the state government on mercury reduction options. Teams of staff and stakeholders are working on reduction strategies and the criteria by which to rank them. The agency will use the council=s advice as one source of information when considering a mercury reduction initiative. The MPCA may develop regulations or recommend legislation as a result.

Title

Description

C. Community-based Voluntary Initiatives

WLSSD Undertakes Amalgam Recycling Initiative

Western Lake Superior Sanitary District (WLSSD) in cooperation with the Northeast District Dental Society has developed recycling procedures for materials containing amalgam particles. Amalgam contains mercury which, if disposed of in solid or medical waste or rinsed to the sewer, could be released to the environment. The first annual amalgam recycling report showed that approximately 522 pounds of waste material containing amalgam was collected for recycling. Eighty eight percent of dental practices responded to the survey conducted by the WLSSD. The Minnesota Dental Association also supports amalgam recycling.

WLSSD Mercury Zero Discharge Pilot Project

Western Lake Superior Sanitary District (WLSSD), the largest wastewater treatment facility discharging to the Lake Superior watershed, is supporting the goal of zero discharge of persistent bioaccumulative toxics by developing a multimedia mercury zero discharge pilot project with hospitals, clinics, educational institutions, laboratories, and dental practices. WLSSD hopes this program will not only test the theory that prevention at the source is more cost-effective than end-of-pipe treatment, but will also ultimately result in the virtual elimination of mercury discharges from these specific business types. In some instances reduced discharge through recycling, on-site treatment, or better management practices may be an interim goal. The specific activities will include documentation of the sources of mercury for the specific business types.

Blueprint for Mercury Elimination

With support from the Great Lakes Protection Fund, the Western Lake Superior Sanitary District (WLSSD) has conducted a Mercury Zero Discharge Project to identify and eliminate sources of mercury to its wastewater treatment plant. The results of the project have been compiled in a Blueprint for Mercury Elimination, designed for use by other wastewater treatment plants in developing and implementing their own mercury reduction programs. It includes information on sources of mercury, successful reduction strategies and case studies, and suggestions for implementing a program. As a result of this project, WLSSD initiated or strengthened pollution prevention partnerships with industries, educational facilities, hospitals, and dentists in its service area and demonstrated that significant mercury reductions in municipal wastewater discharges can be achieved through cooperative partnerships with industry, public education, and disposal facilities.

To date, the Blueprint for Mercury Elimination has been disseminated to over 800 wastewater treatment plants throughout the Great Lake States and Canada. In addition, over 1200 Blueprints have been sent to pretreatment coordinators, government units, environmental agencies and other interested parties throughout the Great Lake States, Canada, and the rest of the United States. The work begun under the Mercury Zero Discharge Project continues with support from the U.S. EPA Great Lakes National Program Office.

Wisconsin Communities Initiate Mercury Reduction Projects

Mercury releases to municipal sanitary sewer systems by hospitals, dental offices, schools, universities, laboratories, other facilities, and homes are largely unregulated. The Wisconsin Department of Natural Resources is working with seven communities to develop and implement mercury reduction programs targeted to these diverse wastewater sources. The programs are designed to educate the population about the impacts of and alternatives to mercury use, collect mercury and mercury products, and provide information about and/or coordinate transporting the mercury to a contractor for recycling.

Pennsylvania Department of Environmental Protection P3ERIE Program

P3ERIE is a voluntary pollution prevention program composed of DEP, businesses, civic organizations, and educational institutions in the greater Erie community. Their mission is "to build support for pollution prevention by developing and implementing a public education campaign and practical projects to reduce the amount of mercury and other persistent toxins that are used and released to the environment in the greater Erie community, especially the Lake Erie watershed." To date, P3ERIE has accomplished the following:

  • collected 1,245 pounds of elemental mercury during a 1998 Earth Day event;

  • distributed 9,000 brochures regarding mercury pollution prevention;

  • worked to encourage northwest Pennsylvania's largest hospital, Hamot Medical Center, to become mercury-free;

  • conducted energy efficiency workshops at the Northwest Pennsylvania Manufacturer's Association; and

  • implemented an active pollution prevention program for school laboratories.

Detroit Water and Sewerage Department (DWSD) PCB/Mercury Minimization Program

Consistent with its ongoing efforts to work with its customers to pilot pollution prevention programs, the DWSD has undertaken a number of special programs to effectively control mercury in hospitals, dental practices, industrial laundries, laboratories, and households. DWSD has initiated an Atmospheric Deposition Study, made revisions to its Local Limits Ordinance, and established an Education/Outreach Program for the general public. The program helps identify current uses of mercury, identify and encourage use of mercury-free alternatives, explore ways to reduce mercury use, coordinate and/or encourage proper disposal practices, and evaluate the effectiveness of voluntary activities to date. In one project under this program, the DWSD developed and coordinated a six-month Bulk Mercury Collection Program in cooperation with the Michigan Dental Association, the National Wildlife Federation, the Michigan Department of Environmental Quality, and the U.S. EPA. More than 400 dentists took advantage of the pro

Mercury Reduction Project for the Greater Milwaukee Area

This project is a joint effort of the Pollution Prevention Partnership, Milwaukee Metropolitan Sewerage District, and Wisconsin Department of Natural Resources. The project has already produced a Mercury Source Sector Assessment Report to help identify important "source sectors," to set priorities for developing cooperative mercury education, technical assistance, and collection programs, and to develop an effective mercury reduction program.

Title

Description

D. Industrial/commercial Voluntary Initiatives

Electric Utility Industry

The amount of coal used by non-utility industry is being reduced through the further electrification of industry throughout the country. Efficient electrical use opportunities are matched and marketed to non-utility coal users to replace coal processes. For example, many efficient electric arc furnaces have replaced basic oxygen furnaces in steel manufacture. The industry estimates that a reduction of more than 15 tons of emitted mercury for commercial and industrial boilers has already resulted.

DTE Energy/Detroit Edison Just-in-Time Arrangements

In response to a 1997 request by the state to reduce storage and eliminate the need for mercury instruments that could be replaced cost-effectively with non-mercury instruments, Detroit Edison, Michigan's largest electric utility, employed just-in-time arrangements for instrumentation and mercury with a supplier. The project will end in December 1998. One ton less mercury is now stored at Detroit Edison facilities.

Consumers Energy Company Undertakes Mercury P2 Initiative

Consumers Energy Company, a Michigan electrical and gas energy and energy services company, began a Mercury Pollution Prevention Initiative in 1996. Mercury is contained in coal used in fuel and is used in plant equipment. The company took action to identify its mercury sources, estimate the total quantity of mercury use, review existing disposal practices, and investigate future management options and costs. The program has heightened awareness of mercury concerns in the company and presented options for use of non-mercury containing equipment. It has also reduced the use of equipment containing mercury and associated stock inventory. In 1996, the program recorded a 231 pound reduction of elemental liquid mercury; in 1997, an additional reduction of 171 pounds was reported.

Niagara Mohawk Power Corporation

Niagara Mohawk Power Corporation, an investor-owned electric and gas utility providing energy to 1.5 million residential, commercial and industrial customers, is committed to the virtual elimination of the use of mercury in its service territory and has established a goal of replacing all mercury containing gas regulators. Since 1995, the company reportedly has committed considerable resources to the elimination of mercury in its systems. The company reports that it has reduced the number of mercury containing gas regulators from approximately 37,500 to approximately 600. The company also reports that it has achieved the U.S. BNS Challenge for Level I substances and that these results surpass the 50 percent reduction target of the Binational Toxics Strategy in the deliberate use of mercury.

Mercury and PCBs: American Electric Power

Since 1987, AEP has voluntarily removed PCBs from its transmission and distribution equipment, including about 4,000 PCB-filled and mineral oil-filled transformers, 15,000 PCB substation capacitors, and 860 other PCB items. AEP's Project Good Turn encourages customers in Ohio, Indiana, and Michigan to turn in second, older working refrigerators and freezers for recycling CFCs and scrap metal, incinerating PCB capacitors, and safe disposal of mercury. AEP reports that it has already recycled more than 40,000 units containing a total of more than 1,000 pounds of PCBs and 80 pounds of mercury.

Battery Industry

In 1984 and 1985, the battery industry accounted for approximately 55% of the total United States consumption of mercury, according to the U.S. Bureau of Mines. Industry-wide initiatives have been taken to decrease the presence of mercury in batteries and battery related mercury contributions to municipal solid waste. New technologies have been introduced which control gassing (which can lead to leakage and possible ruptures) in batteries without the use of mercury. These technologies include: (1) removing or decreasing impurities which cause gassing; (2) using other formulations to suppress gasses and; (3) redesigning the batteries to allow gases to escape at faster rates.

Mercury batteries, which use mercuric oxide as an electrode material, have been replaced by alternatives, such as zinc air batteries, except for a few non-household specialty uses. When alternatives are not available, battery manufacturers provide information so that the battery user can send the used batteries to a properly licensed collection site for recycling or proper disposal.

As a result of these initiatives, the battery industry reports that the United States battery industry's 1994 consumption of mercury was 99.41% less than its 1984 consumption rate (29,700 flasks in 1984, one flask = 76 pounds, to 174 flasks in 1994.) During this same time period, annual sales of alkaline batteries in the United States increased 150%.

Thermostat Recycling Corporation Initiative

In December 1997, the Thermostat Recycling Corporation (TRC) launched a program to recycle mercury-switch thermostats in nine states, including Indiana, Michigan, Minnesota, Ohio, and Wisconsin. The TRC is a private corporation established by thermostat manufacturers, Honeywell, General Electric, and White-Rodgers. Under the program, heating and cooling contractors can drop off old mercury-switch thermostats at participating wholesalers. The wholesalers will collect the thermostats in protective bins provided by TRC and send them to TRC's recycling center where the switches will be removed and forwarded to a mercury recycler. TRC reports that it has processed 50 pounds of mercury in the program's first six months.

Lighting Industry Pushes for Design and Manufacturing Advances

The lighting industry has made significant investments in manufacturing process and new lamp designs to continue to drive down mercury content in lamps. These investments have reportedly reduced the average mercury content of a four foot lamp from 48.2 mg in 1985 to 22.8 mg in 1994. The lamp industry expects to drive mercury content below 12 mg/lamp by the year 2000.

Mercury and PCBs: Consumers Energy Company Launches Replacement Lighting Program

In 1996, Consumers Energy Company launched the "Bottom Line Solutions" replacement lighting program for commercial and industrial customers. The program allows customers to increase their business' lighting while reducing operating and future disposal costs. The new fixtures have efficient, low-mercury lights and non-PCB ballasts.

Mercury and Hexachlorobenzene: The Dow Chemical Company

In support of the Binational Toxics Strategy, The Dow Chemical Company has set a goal for the company to reduce air and water emissions of hexachlorobenzene and mercury compounds by 75 percent by 2005.

Bell Atlantic Mercury Collection Project

Bell Atlantic, a provider of telecommunication services, has instituted a project to collect all mercury relays and switches from old telecommunication equipment. The effort is ongoing with no expected end date. The collected electrical devices are sent to a mercury smelter that safely separates the mercury from the metal casings. On an annual basis, Bell Atlantic collects more than 50,000 pounds of switches and relays containing mercury.

Automobile Pollution Prevention Project

Chrysler Corporation, Ford Motor Company, General Motors Corporation, and the American Automobile Manufacturers Association joined forces in 1991 to form the US Automotive Pollution Prevention Project (or, Auto Project). The project began as a partnership, with the U.S. EPA (Great Lakes National Program Office) funding the Michigan Department of Environmental Quality (DEQ) to launch the project. Now, the auto industry itself is leading the project and making great progress in reducing pollution at the source.

The focus of the project is a group of "Great Lakes Persistent Toxic Substances" (GLPTSs), including Mercury and PCBs. After the first four years, the project has expanded from a concentration on the Great Lakes to a national effort. A similar effort was launched in Canada in 1992.

An integral part of this ongoing effort is the 70 pollution prevention case studies (not all of which pertain to BNS substances) that have been developed by the auto companies. The case studies are available at: http://www.deq.state.mi.us/ead/p2sect/auto/

The American Automobile Manufacturers Association will track emissions of both Binational Toxic Strategy Level I and Level II substances through the U.S. Auto Pollution Prevention Project. EPA Region 5 remains strongly involved through the Auto Project Advisory Group (APAG) which also includes representatives from trade associations, higher education, technology centers, public interest groups, a foundation, and state governments.

General Motors Corporation

Using environmentally conscious design and manufacturing principles, General Motors Midsize & Luxury Car Group (MLCG) facilities replaced mercury switches with ball-type switches used in underhood lamp activation in their 1998 Cadillac and Buick models. The company reports that this change resulted in an estimated elimination of 1,500 pounds of mercury a year from underhood switches. It has been estimated that the mercury contained in underhood and trunk lamp switches accounts for 87% of mercury usage in automotive applications. This amounts to 12.2 million mercury switches containing a total of 8.5 metric tons of mercury per year. MLCG has already eliminated all mercury switches in the trunk lamp activation and replaced these with trunk-ajar switches.

Chrysler Corporation

Chrysler Corporation instituted a project to modify product specifications to: eliminate mercury from equipment; decommission mercury-containing equipment; and evaluate the alternative for blood pressure measurement equipment. The project has resulted in mercury being removed from 20 engineering equipment specifications. The company reports that 1000 pounds of decommissioned mercury were collected in the first year. Mercury-free alternatives to sphygmomanometers were also identified.

Chrysler Corporation

Chrysler has participated in discussions with the Michigan Mercury Pollution Prevention Task Force about mercury use within its facilities and products. The company had discovered in 1995 that mercury is used in underhood switches of certain current models. Chrysler has worked with the American Automobile Association to develop a common approach to identify and remove the mercury switches.

Ford Motor Company

Ford Motor Company reports that it has worked since 1995 to identify feasible alternatives for all mercury switches in all models worldwide and to introduce mercury-free designs in all identified applications as soon as practicable.

Title

Description

E. Special Interest Initiatives

Mercury Information Sheet

Greenpeace Native Lands Campaign and the Indigenous Environmental Network collaborate on several environmental issues. Together, they have produced an information sheet on mercury contamination, its sources and effects.

Community Mercury Reduction Project

As part of the Lake Superior Alliance Sustainable Basin Project, the Central Upper Peninsula Sierra Club was awarded a grant to develop a Community Mercury Reduction Project. Through this grant, the Marquette Community Mercury Reduction Task Force was formed. The Task Force developed recommendations related to: sampling; public education; outreach; ordinances; small businesses; and its own continued efforts. In June 1998, the Marquette Area Wastewater Treatment Facility submitted a grant to EPA Region 5 requesting support to implement the Task Force's efforts to achieve a regional mercury mass balance, continue education and outreach, and implement community mercury reduction activities. The project is designed to be transferrable to other communities in the Great Lakes .

Binational Strategy, Generally: National Wildlife Federation

The National Wildlife Federation (NWF) has promoted the reduction and virtual elimination of Binational Toxics Strategy substances for several years. NWF utilizes a broad range of activities and tools such as hosting workshops, convening special task forces, distributing action alerts and publishing reports and articles on timely topics to educate the public regarding important water quality issues. NWF is working with EPA and state officials to promote the establishment of total maximum daily loads (TMDL) for mercury in regional watersheds.

 

 

Appendix G: Bibliography

 

Ayres, R. J. 1997. Journal of Industrial Ecology, 1, 1, 81-94

Engstrom, Daniel R., and Edward B. Swain, 1997. ARecent Declines in Atmospheric Mercury Deposition in the Upper Midwest,@ Environmental Science and Technology 31, No.4, 960-967.

Federal Register, May 28, 1999. Volume 64, Number 103.

Florida Department of Environmental Protection, 1999 Solid Waste Management Annual Report, August 1999, Chapter 5. http://www.dep.state.fl.us/dwm/documents/swm/swm_99/default.htm

Gilkeson, John, Minnesota Pollution Control Agency, 1996. Mercury Products Study: A report to the U.S. Environmental Protection Agency - Region V.

Jasinski, Stephen M., 1994. The Materials Flow of Mercury in the United States. United States Bureau of Mines Information Circular 9412.

Kearney, AT, 1997. Mercury Treatment and Storage Options Summary Report. Report for U.S. Environmental Protection Agency Region 5.

Lindberg, SE, and J Price, 1999. Measurements of the airborne emissions of mercury from municipal landfill operations: AA short-term study in Florida.@ Journal of Air and Waste Management Association, 49.

Lindberg, SE, et al, 1999. Pathways of Mercury in Solid Waste Disposal, ORNL Sampling Operations Summary and Preliminary Data Report for PaMSWaD-I, Brevard County Landfill. Oak Ridge National Laboratory, Report to the Florida Department of Environmental Protection.

Michigan Mercury Pollution Prevention Task Force, 1996. Mercury Pollution Prevention in Michigan. Michigan Department of Environmental Quality.

Minnesota Pollution Control Agency, 1999. Report on the Mercury Contamination Reduction Initiative Advisory Council=s Results and Recommendations. March 1999. http://www.pca.state.mn.us/hot/legislature/reports/mercury.pdf

North American Task Force on Mercury, 1997. North American Regional Action Plan on Mercury.

SRI International, 1996

Swedish National Chemicals Inspectorate (KEMI), 1997. Mercury in Products - a source of transboundary pollutant transport. November 1997.

U.S. Environmental Protection Agency, 1989. Best Demonstrated Available Technology (BDAT) Background Document for Mercury Wastes.

U.S. Environmental Protection Agency, 1992. Characterization of Products Containing Mercury in the Municipal Solid Waste Stream in the United States, 1970-2000. #530S92013. April, 1992.

U.S. Environmental Protection Agency, 1997a. Mercury Study Report to Congress: White Paper. Office of Air and Radiation. http://www.epa.gov/airprogm/oar/merwhite.html

U.S. Environmental Protection Agency, 1997b. 1997 National Listing of Fish Consumption Advisories.
http://www.epa.gov/ost/fishadvice/

U.S. Environmental Protection Agency, 1999. 1990 Emissions Inventory of Forty Potential Section 112(k) Pollutants. Final Report. Emissions, Monitoring and Analysis Division, and Emission Standards Division, Research Triangle Park.

United States Geological Survey, 1998. Minerals Yearbook
http://minerals.usgs.gov/minerals/pubs/commodity/mercury/430497.pdf

United States Geological Survey, 1999. Mineral Commodity Summary
http://minerals.usgs.gov/minerals/pubs/commodity/mercury/430399.pdf

 

 

Appendix H:
Mercury Waste RCRA Categories

Source: Federal Register, May 28, 1999 (Volume 64, Number 103, pages 28949-28963)

 

D009 Wastes--Characteristic Mercury Wastes. D009 wastes are extremely variable in composition, and depend on the industry and process that generate the waste. Some of the more common types of D009 wastes include miscellaneous wastes from chlor-alkali production facilities (especially cell room trench sludge and activated carbon for liquid or gas purification), used fluorescent lamps, batteries, switches, and thermometers. D009 wastes are also generated in the production of organomercury compounds for fungicide/bactericide and pharmaceutical uses, and during organic chemicals manufacturing where mercuric chloride catalyst is used.(1)

Mercury concentrations within D009 wastes may range from 0.20 mg/L TCLP [toxicity characteristic leachate procedure] to greater than 75 percent of the total waste composition. D009 wastes may also contain organic compounds, usually when mixed with solvent wastes.

Although characterization data for D009 wastes are limited, some conclusions can be made regarding potential treatment concerns. Wastes with greater than 500 ppm 40 CFR part 261, appendix VIII organics (such as benzene) may be problematic for commercial retorting facilities due to the permitting requirements for boiler and industrial furnaces (BIF) (40 CFR 266.100(c)). At least two facilities are unable to handle wastes with these levels of volatile organics due to the additional permitting that would be required. However, these two facilities are capable of treating non-volatile activated carbons.

K071 Wastes--Brine purification muds from the mercury cell process in chlorine production, where separately prepurified brine is not used. K071 wastes are generated by the chlor-alkali industry in the mercury cell process. In this process, sodium chloride is dissolved to form a saturated brine solution. The brine solution is purified by precipitation, using hydroxides, carbonates, or sulfates. The precipitate is dewatered to form K071 wastes, while the purified brine continues in the process. The depleted solution from the mercury cell is ultimately recycled to the initial step of the process.

Available analytical information for K071 brine purification muds show that these wastes consist primarily of inorganic solids and water. The normal total mercury content of K071 wastes is less than 100 parts per million (ppm) and is normally characterized as metallic mercury or soluble mercuric chloride.(2) Mercury from K071 wastes is typically recovered using a wet process, reflecting the BDAT for this waste.

K106 Wastes--Wastewater treatment sludge from the mercury cell process in chlorine production. Like K071 wastes, K106 wastes are generated from chlorine production using the mercury cell process. Effluent from the mercury cell includes spent brine, a portion of which is recycled and a portion of which is purged to wastewater treatment. Other plant area wastewaters (e.g., stormwater, washdown waters) are also typically sent to this treatment system. The wastewater treatment process generates a sludge through precipitation and filtering, which is K106 waste. Sulfides (as either sodium sulfide, Na2S, and/or sodium bisulfide, NaHS) have been commonly used as a precipitation agent for at least the last 10 years (1988 to 1998), according to data from the Chlorine Institute. Sludges generated in this manner are comprised, in part, of mercuric sulfide. Other (minor) precipitation agents result in the formation of mercury hydroxide or in elemental mercury. However, sulfide precipitation is preferable to hydroxide precipitation using hydrazine because mercury hydroxide is susceptible to matrix dissolution over a wide range of pH under oxidizing conditions.

Available analytical information for K106 wastes indicates they are primarily composed of water and diatomaceous earth filter aid. This is true for K106 wastes generated by both sulfide treatment and hydrazine treatment. K106 wastes from sulfide precipitation contain approximately 4.4 percent mercury, as mercuric sulfide, while K106 wastes from hydrazine treatment contain approximately 0.5 percent mercury, as mercurous hydroxide.(3)

The mercury concentration in K106 waste is consistently greater than 260 mg/kg and therefore retorting is a required technology for this waste. K106 waste also contains significant levels of sulfides sulfates, sodium chloride, and organics, although the mercury is likely in an elemental or a sulfide form.

P065 Wastes--Mercury fulminate. P065 wastes consist of discarded mercury fulminate product, off-specification mercury fulminate product, and container or spill residues thereof. No waste characterization data were available for P065 listed wastes. The quantity of P065 waste is expected to have declined, as the military has phased out its use in explosives.(4)

P092 Wastes--Phenylmercury acetate. P092 wastes consist of discarded phenylmercury acetate product, off-specification phenylmercury acetate product, and container or spill residues thereof. There are very little data available on the composition of P092 listed wastes. The primary constituent of P092 listed wastes is phenylmercury acetate; organic constituents (in particular, benzene) are also expected to be present.(5)  The use of phenylmercury acetate as a preservative in latex paint was phased out in 1991. Thus, the quantity of P092 waste is expected to decline dramatically as the stock of mercury-bearing paint is depleted.(6)

U151 Wastes--Mercury. U151 wastes consist of discarded elemental mercury product, off-specification metallic mercury product, and container or spill residues thereof. The majority of U151 wastes reported as a single waste code (i.e., not mixed with other listed or characteristic wastes) in the EPA 1986 Generator Survey are over 50 percent mercury. The principal constituent of U151 is metallic mercury.(7)

 

FOOTNOTES:

(1)  US EPA, 1989, pages 2-8

(2)  US EPA, 1989, pages 2-11

(3)  US EPA, 1989, pages 2-11

(4)  Kearney, 1997, page 1

(5)  US EPA, 1989, pages 2-17

(6)  Kearney, 1997, page 1

(7)  US EPA, 1989, pages 2-17

 

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